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DL-1,2-Isopropylideneglycerol

CAS No.: 100-79-8      Formula: C6H12O3

Weight: 132.15800

Synonyms: (±)-2,2-Dimethyl-4-hydroxymethyl-1,3-dioxolane; 1,2-Isopropylideneglycerol; 1,3-Dioxolane-4-methanol, 2,2-dimethyl-; 2,2-Dimethyl-1,3-dioxolane-4-methanol; Solketal; 1,2-O-Isopropylideneglycerol; 2,2-Dimethyl-4-hydroxymethyl-1,3-dioxolane; 1,2-Isopropylidene-rac-glycerol; (±)-2,2-Dimethyl-1,3-dioxolane-4-methanol;


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Description

Solketal is a protected form of glycerol with an isopropylidene acetal group joining two neighboring hydroxyl groups. Solketal contains a chiral center on the center carbon of the glycerol backbone, and so can be purchased as either the racemate or as one of the two enantiomers. Solketal has been used extensively in the synthesis of mono-, di- and triglycerides by ester bond formation. The free hydroxyl groups of solketal can be esterified with a carboxylic acid to form the protected monoglyceride, where the isopropylene group can then be removed using an acid catalyst in aqueous or alcoholic medium. The unprotected diol can then be esterified further to form either the di- or triglyceride.

Basic Information
CAS No.:
100-79-8
Synonyms:
(±)-2,2-Dimethyl-4-hydroxymethyl-1,3-dioxolane; 1,2-Isopropylideneglycerol; 1,3-Dioxolane-4-methanol, 2,2-dimethyl-; 2,2-Dimethyl-1,3-dioxolane-4-methanol; Solketal; 1,2-O-Isopropylideneglycerol; 2,2-Dimethyl-4-hydroxymethyl-1,3-dioxolane; 1,2-Isopropylidene-rac-glycerol; (±)-2,2-Dimethyl-1,3-dioxolane-4-methanol;
Formula:
C6H12O3
Molecular Weight:
132.15800
PSA:
38.69000
LogP:
0.13020
Properties
Appearance & Character:
Liquid, Clear colorless
Density:
1.034g/cm3
Melting Point:
-27℃
Boiling Point:
188.5°C at 760 mmHg
Flash Point:
80ºC
Storage Conditions:
Sealed in dry,2-8°C
Safety Info
Customs Code:
29329970
WGK Germany:
2
Hazard Category Code:
R36/37/38
Security Instructions:
S24/25
Dangerous Goods Sign:
Xi