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(R,R)-N-(p-Toluenesulfonyl)-1,2-diphenylethylenediamine

CAS No.: 144222-34-4      Formula: C21H22N2O2S

Weight: 366.47700

Synonyms: (1R,2R)-(-)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine; Benzenesulfonamide,N-[(1R,2R)-2-amino-1,2-diphenyl; (R,R)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide; (R,R)-Tsdpen; N-[(1R,2R)-2-amino-1,2-diphenylethyl]-4-methylbenzenesulfonamide; (1R,2R)-(-)-N-(4-Toluenesulfonyl)-1,2- Diphenylethylenediamine; (1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine; N-((1R,2R)-2-Amino-1,2-diphenylethyl)-4-methylbenzenesulfonamide;


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Description

1,2-Diphenylethylenediamine is a useful intermediate of pharmaceutical and chemical raw materials. Optically active 1,2-diphenylethylenediamine is an important chiral reagent with symmetry. It can be used to Optical resolution of acid chiral compounds, the compound is also widely used in asymmetric synthesis such as: asymmetric hydroxylation of alkenes, asymmetric aldol condensation reaction Chemicalbook, asymmetric Diels-Alder reaction, asymmetric carbonyl Allylation reaction, formation of optically active propadienyl alcohol and propynyl alcohol, asymmetric epoxidation of alkenes without functional groups, etc. (1R,2R)-(-)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine is its N-p-toluenesulfonyl substitution product.

Basic Information
CAS No.:144222-34-4
Synonyms:(1R,2R)-(-)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine; Benzenesulfonamide,N-[(1R,2R)-2-amino-1,2-diphenyl; (R,R)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide; (R,R)-Tsdpen; N-[(1R,2R)-2-amino-1,2-diphenylethyl]-4-methylbenzenesulfonamide; (1R,2R)-(-)-N-(4-Toluenesulfonyl)-1,2- Diphenylethylenediamine; (1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine; N-((1R,2R)-2-Amino-1,2-diphenylethyl)-4-methylbenzenesulfonamide;
Formula:C21H22N2O2S
Molecular Weight:366.47700
PSA:80.57000
LogP:5.88660
Properties
Appearance & Character:Crystals or Crystalline Powder, White to slightly yellow
Density:1.1440 (rough estimate)
Melting Point:128-131 °C(lit.)
Boiling Point:537.3±60.0 °C(Predicted)
Flash Point:
Storage Conditions:Keep in dark place,Inert atmosphere,Room temperature
Safety Info
Customs Code:29215900
WGK Germany:3
Hazard Category Code:36/37/38
Security Instructions:26-36
Dangerous Goods Sign:Xi
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