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(Carbethoxymethylene)triphenylphosphorane

CAS No.: 1099-45-2      Formula: C22H21O2P

Weight: 348.37500

Synonyms: (Triphenylphosphoranylidene)acetic Acid Ethyl Ester; (Ethoxycarbonylmethylene)triphenylphosphorane; (Triphenylphosphoranylidene)acetic; ethyl 2-(triphenyl-λ<sup>5</sup>-phosphanylidene)acetate; Ethyl (Triphenylphosphoranylidene)Acetate; Ethyl 2-(triphenylphosphoranylidene)acetate;




Description

Triphenylcarbethoxymethylenephosphorane is an organophosphorus compound with the chemical formula Ph3PCHCO2Et (Ph = phenyl, Et = ethyl). It is a white solid that is soluble in organic solvents. The compound is a Wittig reagent. It is used to replace oxygen centres in ketones and aldehydes with CHCO2Et.

Basic Information
CAS No.:
1099-45-2
Synonyms:
(Triphenylphosphoranylidene)acetic Acid Ethyl Ester; (Ethoxycarbonylmethylene)triphenylphosphorane; (Triphenylphosphoranylidene)acetic; ethyl 2-(triphenyl-λ<sup>5</sup>-phosphanylidene)acetate; Ethyl (Triphenylphosphoranylidene)Acetate; Ethyl 2-(triphenylphosphoranylidene)acetate;
Formula:
C22H21O2P
Molecular Weight:
348.37500
PSA:
36.11000
LogP:
3.34580
Properties
Appearance & Character:
Powder, White to light yellow
Density:
1.086 g/cm³
Melting Point:
123.5-125.5 °C
Boiling Point:
490.4ºCat 760 mmHg
Flash Point:
Storage Conditions:
2-8°C
Safety Info
Customs Code:
29310095
WGK Germany:
3
Hazard Category Code:
R25; R36/37/38
Security Instructions:
S22-S24/25-S45-S37/39-S26
Dangerous Goods Sign:
T