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(1R,2R)-(+)-1,2-Diphenylethylenediamine

CAS No.: 35132-20-8      Formula: C14H16N2

Weight: 212.29000

Synonyms: (1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediamine; (1R,2R)-1,2-Diphenylethane-1,2-diamine; (1R,2R)-1,2-Diphenyl-1,2-ethanediamine; (1R,2R)-(+)-1,2-Diphenylethylenediamine; (1R,2R)-(+)-1,2-Diphenyl-1,2-Ethanediamine ee; (1R,2R)-(+)-1,2-Diamino-1,2-diphenylethane;


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Description

It is an important chiral reagent with a C2-axis of symmetry. At present, it has been widely used in asymmetric synthesis and optical resolution, such as asymmetric epoxidation reaction of non-functionalized alkenes, asymmetric aldol condensation reaction, asymmetric DieChemicalbookls-Alder reaction, asymmetric allylation reaction of carbonyl, Synthesis of optically active propadienyl alcohol and propynyl alcohol, asymmetric epoxidation of alkenes without functional groups, resolution of binaphthol, etc.

Basic Information
CAS No.:
35132-20-8
Synonyms:
(1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediamine; (1R,2R)-1,2-Diphenylethane-1,2-diamine; (1R,2R)-1,2-Diphenyl-1,2-ethanediamine; (1R,2R)-(+)-1,2-Diphenylethylenediamine; (1R,2R)-(+)-1,2-Diphenyl-1,2-Ethanediamine ee; (1R,2R)-(+)-1,2-Diamino-1,2-diphenylethane;
Formula:
C14H16N2
Molecular Weight:
212.29000
PSA:
52.04000
LogP:
3.78700
Properties
Appearance & Character:
White to light yellow
Density:
1.106 g/cm³
Melting Point:
81-84ºC
Boiling Point:
353.9ºC at 760 mmHg
Flash Point:
199.9ºC
Storage Conditions:
Keep in dark place,Inert atmosphere,Room temperature
Safety Info
Customs Code:
2942000000
WGK Germany:
3
Hazard Category Code:
R36/37/38
Security Instructions:
S26-S36
Dangerous Goods Sign:
Xi